Methanol is produced from syngas via the fischertropsch process, given by eqn. Highquality failure analysis and good engineering judgment can turn plant shutdowns resulting from methanol reformer tube failures into an opportunity to improve the future performance of the reformer furnace. Hello, ive been asked to design a primary reformer for the extraction of hydrogen from methane for haber bosch process final year project. Methanol reformer design considerations hansen major. Design of a methanol to hydrogen microreformer for fuel. Equipment design and cost estimation for small modular. Methanol is transformed into hydrogen and carbon dioxide by pressure and heat and interaction with a catalyst. These may support the production of ammonia, methanol, gas. The fuel reformer consists of feed preheating unit, autothermal reformer, oxygen removal reactor, steam reformer, high. Carbon monoxide is a poison for polymer electrolyte membrane pem fuel cells, thus if this kind of fuel cell is used, the carbon monoxide concentration must be reduced to a very low level, typically less than 100 ppm.
Video game called reformer, a sandbox type video game catalytic reformer, a unit in an oil refinery that reforms lighter hydrocarbons into higher octane molecules and hydrogen. Hydrogen can be extracted by the reforming process from methanol, natural gas, fossil fuel etc. This paper describes the design, start up and the initial operation of the 2,400 mtpd methanol plant at. Rover cars company addressed manufacturing and vehicle design issues, and instituto. Segmented coating design in a microchannel methanol reformer is investigated. The reactor designs based on steam reforming alone mainly differ with respect to the method by which the heat is provided for the endothermal overall reaction.
Methanol reformers operate on a convenient mix of methanol with water and require little electric power. Methanol reforming typically takes place at 220300 degrees celsius and is an endothermic process, meaning that we need to add thermal energy to drive the process. Hawkins managing director, ceo c2pt catalyst process technology. Reformers for the production of hydrogen from methanol and. A large fraction of this methanol is recovered in the foul condensate steam stripping system. The heat of the flue gases is usually utilized in the convective part of the reformer by generating steam and preheating the feedstock, thus bringing the overall thermal efficiency to over 85%. Accepted for publication in chemical engineering and technology. Process design overview for upgrading a gastomethanol facility. In consideration of this location, it was decided to take the. Modeling and design of a multitubular packedbed reactor for. The 2400 mtpd methanol plant at tjeldbergodden new fuel as. Design and control of a methanol reactorcolumn process. Louzeiro nr1, mavinic ds, oldham wk, meisen a, gardner is. Three different methanol reformer designs for thermal integration with an htpemfc were thoroughly studied experimentally and by cfd simulation.
This supercharged and turbocharged sparkignition engine combines a methanol reforming system with the direct injection of methanol fuel to extend the efficiency of internal combustion engines to more than 40% over conventional gas engines, and to more than 10% over clean diesel and typical gasolineelectric hybrid vehicles. Partial oxidation reforming of methanol conference osti. This methanolfueled engine system uses direct injection during highload operation and, during lowload operation, sends a fraction of the fuel to an inengine methanol reformer to generate a hydrogenrich gas that improves combustion stability by speeding up the combustion process. Design of compact methanol reformer for hydrogen with low co for the fuel cell power generation article in international journal of hydrogen energy 379. The conversion study of the methanol water mixture was made using the system shown in figure 1, which is composed by a reservoir of 200 ml containing a methanol water mixture, a peristaltic pump, an evaporator and the reformer both inside an electrical heated furnace.
Developmentcommercialization status of methanol steam reformers. A wide variety of methanol reformer options are available to you, there are 186 suppliers who sells methanol reformer on, mainly located in asia. Methanol can be produced from co 2 in two different ways. There are a couple of types of steam reformers, one reforming methanol and the other reforming natural gas. Reformer enhanced direct injection methanol engines improve e. Increases in unconventional oil and gas production have substantially reduced the united states dependence on foreign crude. His masters thesis was titled fuel processing catalysis for microchannel applications. Methanol steam reformer high temperature pem fuel cell. A dynamic model for the design of methanol to hydrogen. Internal combustion engine efficiency with methanol reforming. The top countries of supplier is china, from which the percentage of methanol reformer supply is 95% respectively.
Design and development of an autothermal reformer for fuel cell applications. A dynamic model for the design of methanol to hydrogen steam. Methanol is a liquid fuel that is light, colorless, stable, and biodegradable methanol contains more hydrogen than any other liquid fuel methanol can be sourced regionally, and is produced globally at over 90 plants producing almost 24 billion gallons annually methanol is easily mixed with purified water in a batch process by local. The subject technology is a hydrogen generation system design for stationary fuel cell power systems. I just want to know how i would use this information to design the reformer. Transient behaviour of a small methanol reformer for fuel.
There are a number of considerations in the design of fuel reforming systems 1. The number of mesh elements varies from 56,100 to 345,460 depending on the geometry of the computational domain. A new design for a microchannel methanol steam reformer has been developed to provide power in conjunction with a micro fuel cell for a portable, lowpower device. Steam to methanol ratio setup there is a general consensus that the most active and selective catalysts for the endothermic srm reaction are cuo znoal 2 o 3 based catalysts 14, hence the same type of catalyst was chosen for our simulations. Design and control of a methanol reactorcolumn process william l. Steam reformer furnace design will continue to develop along with methods to. Methanol steam reformer high temperature pem fuel cell system. Pdf modeling and design of a multitubular packedbed reactor.
Some design considerations for a catalytic methanol steam reformer for a pem fuel cell power generating system, the 26th intersociety energy conversion engineering conference 3, proceedings, pp. Methanol steam reforming for hydrogen production chemical. The mesh independency with a convergence criteria of 10. Design of compact methanol reformer for hydrogen with low. With gas and oil prices subject to fluctuation in response to political instability within regions home to most of the worlds petroleum reserves, the pursuit of costeffective alternative fuel sources such as natural gas has escalated. Design and implementation of an opticalaccess steam methanol. Optimal design of an experimental methanol fuel reformer chihchiang chuanga, yihhang chenb, jeffrey d. Methanol reformer development and testing for integration. Steam reforming of methanol for fuel cell grade hydrogen.
In describing methanol steam reforming, we have limited our. He later obtained his masters degree in chemical engineering, also from washington state university, in 2005. The plant is located in beaumont, texas and was built in 1967 by dupont with an original capacity of 550 metric mtpy of methanol from natural gas. Org 500 mtpd of co2 is recovered from the flue gas using mhis proprietary ks1 solvent and injected in synthesis loop for boosting methanol production. Internal combustion engine efficiency with methanol. Process control and design considerations for methanol. The design is optimized for low pumping power and rapid operation as well as thermal efficiency, overall size, and complete generation of the available hydrogen. Control structure design for methanol process at ntnu. Simultaneous production of methanol and dimethylether from. Wasserstoffgewinnung aus methanol fuer pembrennstoffzellen. The steam reformer how fuel processors work howstuffworks. A nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst. Methanol steam reforming msr reaction occurs simultaneously with two. High yields of hydrogen production from methanol steam reforming.
A steam reformer better lends itself to thermal integration with the fuel cell system. Catalyst layer design and arrangement to improve the. Process control and design considerations for methanolinduced denitrification in a sequencing batch reactor. Compact, inexpensive microreformers for distributed gasto. Methanol production from biogas could also increase by 9. Methanol steam reforming in a dual bed membrane reactor for. Only a portion of the steam generated in the boiler is. Methanol is very commonly used as a feedstock in the chemical industries. Using these basic considerations as guidelines, different reactor designs are discussed and examples given. Chapter 1 introduction this thesis presents a master of science degree project conducted at the department of chemical engineering, at ntnu. For onboard reforming, the reformer must be compact and lightweight, and have rapid startup and.
A key advantage of the design is the use of a methanol fuel reformer to generate up to 99. A kinetic langmuirhinshelwood model of the methanol steam reforming. Comparison of efficiency between systems with a high temperature ht pemfc stack and a classical, lowtemperature lt pemfc stack has been made. The process was therefore not just a method of synthesising methanol. In two steps conversion, co 2 is first converted into co through the reverse water gas shift rwgs reaction and then hydrogenated to methanol. Simultaneous production of methanol and dimethylether from synthesis gas doctoral thesis submitted to the department of chemical engineering of the university of patras by siranush akarmazyan in partial fulfilment of the requirements for the. Jul 30, 20 on most methanol plants we only have a primary reformer therefore must minimize methane slip from primary methane is an inert in the loop just like ammonia represents an inefficiency must be purged out lose reactants purge is burned in reformer typically 23 of the reformer fuel some plant do sell it. Balance of plant considerations for stationary, transportable, and. Therefore a cfd analysis was carried out using commercial software. Development of a methanol reformer for fuel cell vehicles. Partial oxidation reforming of methanol conference. Both steam reforming and partial oxidation with steam, air and methanol are considered.
With a reformer, the main design considerations are its physical dimensions, its response rate after cold start and its transient response during acceleration. What is methanol reformer methanol reformer is an apparatus used especially in the process of converting fuel into electricity through an electrochemical reaction of hydrogen fuel with oxygen or another oxidizing agent. An overview is presented here of the major process design considerations evaluated and implemented for the upgrade of an existing naturalgastomethanol plant. Lets get to 100 mvs engineering started this petition to heavy equipment what is methanol methanol often abbreviated as meoh is a combustible volatile and achromatic liquid which is extremely harmful or poisonous in nature. The newly developed reforming catalyst will operate at 180 c, which enables the.
On most methanol plants we only have a primary reformer therefore must minimize methane slip from primary methane is an inert in the loop just like ammonia represents an inefficiency must be purged out lose reactants purge is burned in reformer typically 23 of the reformer fuel some plant do sell it. The thesis studies the simulation, optimization and control structure design using stepwise approach of skogestad. There are no significant byproducts or intermediates. With a reformer, the main design considerations are its physical dimensions, its response rate after.
Luyben department of chemical engineering, lehigh university, bethlehem, pennsylvania 18015 methanol is one of the prime candidates for providing an alternative to petroleumbased liquid transportation. Process design overview for upgrading a gastomethanol. Modelling in methanol synthesis university of oulu. Methanol steam reforming and selective co methanation.
Methanol to hydrogen generation technology for stationary. A co 2 to methanol process was designed and simulated with aspen plus the methanol plant provides 36% of the steam necessary to co 2 capture the yield is 0. The one step conversion is the direct hydrogenation of co 2 to methanol. Sep 24, 20 steam reforming types of reformer design 1. Study of different designs of methanol steam reformers. Design of compact methanol reformer for hydrogen with low co. In both systems the methanol reformer operates at 250 c and steamtomethanol ratio of 1. Frameworks new software that predicts hydrate properties and its use in gas hydrate studies. Catalytic oxidation of liquid methanol as a heat source for an automotive reformer. The capacity of methanol plant has increased by 300 mtpd with addition of co2 in synthesis gas mixture as excess h2 is available for the methanol reaction. Nonsyngas direct steam reforming of methanol to hydrogen. Temperature measurements have been taken along the reformer axis in order.
Inside and outside the methanol reformer there are two guide. A data acquisition system was developed based on labview software national. Methanol reformer and its advantages 0 have signed. With good design of the steam reformer such composition of the reformate gas is not too difficult to achieve. At last, microchannel reformer exhibited the highest methanol conversion among the reactors. The process starts with the vaporization of liquid methanol and water. It represents the uncomplicated or simplest alcohol with chemical. Design and simulation of a methanol production plant from. The goal of the reformer is to remove as much of the hydrogen h as possible from this molecule. Three major types of reformer each tackles the duty in different ways no clear. Methane reformer a unit for producing hydrogen from methane. The goal of the reformer is to remove as much of the hydrogen h as possible from this molecule, while minimizing the emission of pollutants such as carbon monoxide co. Steam reformer a unit for converting natural gas into hydrogen and carbon. With the surge in natural gas production in the us, gastomethanol plants are receiving renewed interest.
Reformer furnace outlet systems 3 background the issue steam. Reformer is currently a video game being developed reformer may also refer to. Reformer furnace outlet systems 6 methane slip in the 5. It should be noted that there are other industries, such as ammonia and methanol production, that operate. The details of the software used to develop the steadystate and dynamic models of. Compact, inexpensive microreformers for distributed gas. Methanol is an attractive fuel for fuel cellpowered vehicles because it has a fairly high energy density, can be pumped into the tank of a vehicle mush like gasoline, and is relatively easy to reform. Transient behaviour of a small methanol reformer for fuel cell during hydrogen production after cold start. This paper describes the development work of a methanol steam reformer test bench and the reformer design work. Methanol reformers are large largest reformer has 960 tubes two. Brown off and mixed with some natural gas and steam reformed in a small furnace which is about of the size of one for a totally natural gas based plant.
A new design for a microchannel methanolsteam reformer has been developed to provide power in conjunction with a micro fuel cell for a portable, lowpower device. Design of a methanol to hydrogen microreformer for fuel cell. Review of small stationary reformers for hydrogen production. Tubular reformer for methanol plant based on two step reforming.
The results showed that the multichannel design is the best solution for the thermal integration, with high methanol conversion and low pressure drop. Design and implementation of an opticalaccess steam. Methanol is produced as a byproduct of the kraft pulping process. Methanol steam reforming for fuel cell applications. Pdf study of different designs of methanol steam reformers. Failure analysis and remaining life assessment of methanol. A methanol reformer is a device used in chemical engineering, especially in the area of fuel cell technology, which can produce pure hydrogen gas and carbon dioxide by reacting a methanol and water steam mixture. Optimal design of an experimental methanol fuel reformer. The most important is the conversion of methane in the reformer.
Design and simulation of a methanol production plant from co2. Aspen or a similar process modeling software, and refueling station designs. The stripper off gas sog is condensed to produce a crude methanol solution, which is upgraded to minimum 99. Modeling internal combustion engine with thermochemical. Review of synthesis gas processes ferdowsi university of. Due to the relatively low reforming temperature of methanol, the use of a methanol reformer in combination with an htpem fuel cell leads to several benefits. We have been committed to catalytic process technology for more than 70 years.
1288 828 927 789 1204 913 1411 615 238 146 273 557 105 136 736 460 1045 445 396 862 1433 1493 1573 984 1404 1416 320 1327 702 664 445 661 1038 1307 515